Seems relatively useless to me. Suffers from the same problem as Chatroulete. Everyone just nexts you. No lasting conversations. It seems like you should gentle introduce ppl rather than just showing them a video feed of each other.
I should add: I'm looking for these episodes relatively quickly after they're aired. The PB links I get when I google for stuff don't seem to be for recent episodes.
A friend of mine generally finds a link through his own sources relatively quickly and shares it, though.